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Are PU spray foam machines toxic or flammable?

The complexity of polyurethane (PU) spray foam applications extends beyond their insulation benefits to significant safety considerations that every operator must understand. Both toxicity and flammability risks are inherent in these systems, stemming from their chemical components, application processes, and the properties of both uncured and cured materials.

Key Takeaways:

  • Isocyanates in spray foam present serious respiratory hazards requiring proper respiratory protection
  • PU foam components can be flammable during application, with chemical reactions generating heat that poses fire risks
  • Comprehensive ventilation systems and strict reentry timing protocols are essential for safe application
  • Proper personal protective equipment including full-body protection and respirators significantly reduces exposure risks
  • Regular equipment maintenance and worker certification are critical for minimizing safety hazards

Understanding the Safety Profile of PU Spray Foam Machines

Polyurethane (PU) spray foam has revolutionized the insulation industry with its superior thermal resistance and air-sealing capabilities. This versatile material consists primarily of two reactive components—isocyanates and polyols—that chemically combine during application to form the final expanded foam product. When applied using specialized PU spray foam machines, these chemicals react rapidly, expanding up to 100 times their liquid volume.

The application process involves heating and pressurizing these chemicals before they're mixed at the spray gun tip. This reactive chemistry creates both the beneficial properties of spray foam and the potential safety hazards that must be addressed. The primary concerns fall into two categories: toxicity from chemical exposure during application and curing, and flammability risks associated with the materials and application process.

Understanding these risks isn't merely academic—it directly impacts the safety of applicators, nearby workers, building occupants, and property. According to the Spray Polyurethane Foam Alliance (SPFA), proper safety protocols can dramatically reduce these risks while still allowing for the benefits of this effective insulation technology.

Chemical Hazards: The Toxic Reality of Spray Foam Components

The chemical composition of spray polyurethane foam presents significant health concerns that every applicator should fully understand. The "A-side" component typically contains methylene diphenyl diisocyanate (MDI) and other isocyanate compounds that are highly reactive chemicals. The "B-side" contains polyols, flame retardants, catalysts, and blowing agents that complete the chemical reaction.

During application, these components react to form the final polyurethane product, but in their unreacted state, they pose various health risks. Isocyanates are particularly concerning as they're powerful irritants and sensitizing agents for the respiratory system. According to the National Institute for Occupational Safety and Health (NIOSH), isocyanates are a leading cause of occupational asthma.

The chemical formulations vary between manufacturers and specific product lines, with some offering reduced toxicity profiles. However, even "green" or "eco-friendly" formulations still contain chemicals that require appropriate safety measures. The Environmental Protection Agency (EPA) notes that no spray foam system is entirely free from potential health hazards during application.

This chemical complexity makes understanding the toxic potential of PU foam materials essential for anyone working with or around these systems.

Respiratory Risks from Isocyanate Exposure

Isocyanate exposure represents the most serious health hazard associated with spray foam operations. When inhaled, these chemicals can cause immediate respiratory distress including coughing, shortness of breath, and chest tightness. The Occupational Safety and Health Administration (OSHA) has established specific exposure limits for isocyanates, yet studies show these limits are frequently exceeded in real-world applications without proper controls.

The long-term consequences of isocyanate exposure can be devastating. Once sensitized to isocyanates, a worker may develop permanent asthma-like symptoms that can be triggered by even minimal future exposures—sometimes below detectable levels. This condition can end an applicator's career and cause lifelong health difficulties.

A CDC study of spray foam applicators found that approximately 15% developed isocyanate sensitization within five years of work, indicating the prevalence of this occupational hazard. Proper respiratory protection isn't optional—it's essential for preventing both acute and chronic health effects.

The toxic fumes from polyurethane spray machines can spread beyond the immediate application area, potentially affecting others in the building. This highlights the need for isolation of work areas and comprehensive ventilation systems that protect everyone in the vicinity.

Skin and Eye Irritation from Spray Foam Chemicals

Direct contact with spray foam components can cause significant dermal and ocular damage. Isocyanates and other chemicals in the spray foam formulation can penetrate the skin, causing irritation, rashes, and chemical burns. More concerning is their ability to trigger allergic contact dermatitis, a condition where the immune system becomes sensitized to these chemicals, resulting in increasingly severe reactions with each exposure.

Eye exposure is particularly dangerous, with chemical splashes potentially causing severe irritation, corneal damage, or even permanent vision impairment. Documentation from medical case reports shows that eye injuries often result from improper or inadequate eye protection during application or equipment maintenance.

The Centers for Disease Control and Prevention (CDC) reports that skin absorption of isocyanates may also contribute to respiratory sensitization, meaning that protecting the skin isn't just about preventing rashes—it's also about reducing the risk of developing respiratory issues.

Appropriate chemical-resistant gloves, full-body coveralls, and proper eye protection are essential safeguards. These items must be specifically rated for isocyanate resistance, as standard work gear often provides inadequate protection against these aggressive chemicals.

Volatile Organic Compounds (VOCs) in Spray Foam Systems

Beyond isocyanates, spray foam systems release various volatile organic compounds during application and curing. These VOCs can include flame retardants, catalysts, and blowing agents that become airborne during the spraying process. The EPA has identified numerous VOCs in spray foam emissions, including certain compounds classified as probable carcinogens.

Indoor air quality can be significantly compromised during and after spray foam installation. Studies measuring VOC levels during application have recorded concentrations far exceeding recommended exposure limits. These elevated levels can persist for hours or days after application, depending on ventilation, temperature, humidity, and the specific formulation used.

Health effects from VOC exposure include headaches, dizziness, nausea, fatigue, and eye/throat irritation. Chronic exposure to certain VOCs has been linked to liver and kidney damage, central nervous system effects, and increased cancer risk according to the Environmental Protection Agency.

Professional spray foam contractors use specialized instruments like photoionization detectors (PIDs) and sorbent tubes to measure VOC concentration levels. These testing methods help determine when it's safe for unprotected workers or occupants to re-enter spaces after foam application.

Flammability Concerns: Separating Fact from Fiction

A common question in the industry is: "Are PU spray foam machines flammable?" The answer requires understanding the distinct fire risks at different stages of the application process. The raw components themselves have varying flammability profiles—some are classified as combustible liquids rather than flammable ones, but all require proper handling.

Uncured spray foam presents heightened fire risks compared to the fully cured product. During application, the exothermic reaction generating heat, combined with flammable propellants and solvents, creates conditions where ignition sources must be strictly controlled. Once fully cured, most spray foams are classified as combustible rather than flammable materials, typically achieving a Class I or II fire rating.

However, cured foam isn't without fire hazards. Certain heat-generating activities like cutting with torches, soldering, or grinding near installed foam can ignite the material or cause it to smolder. A study by Underwriters Laboratories found that foam exposed to temperatures above 700°F can ignite and propagate fire rapidly.

The National Fire Protection Association (NFPA) has documented incidents where improper application of spray foam—particularly when applied too thickly in a single pass—generated excessive heat that led to spontaneous combustion within the foam mass. This highlights the critical nature of following manufacturer guidelines for application thickness and curing times.

Chemical Fire Hazards During Application

The spray foam equipment flammability risks are most acute during the active application process. Certain components in the chemical formulation, particularly hydrocarbon-based blowing agents, have flash points low enough to present genuine fire dangers. When aerosolized through the spray process, these compounds become even more susceptible to ignition.

The temperature thresholds for ignition vary by formulation but typically range between 200-400°F for many spray foam components. The chemical reaction itself generates heat—sometimes reaching 150-200°F within the foam mass—which approaches dangerous levels if application parameters aren't carefully controlled.

Emergency protocols for chemical fires must be established before beginning any spray foam project. These fires require specific extinguishing agents and approaches, as water can sometimes spread chemical fires or react with certain components to create additional hazards.

The Spray Polyurethane Foam Alliance has documented multiple incidents where electrical sparks from equipment, static electricity, or nearby hot work ignited spray foam components during application. These incidents underscore the importance of proper training and equipment selection for safe operations.

Toxic Emissions Under Heat Stress

When cured polyurethane foam is subjected to high temperatures—whether through fire, hot work activities, or even excessive heat during renovation—it breaks down and releases highly toxic decomposition products. These include hydrogen cyanide, isocyanates, carbon monoxide, and various nitrogen oxides that pose immediate dangers to life and health.

Construction activities that generate heat near installed foam create particularly hazardous conditions. Sawing with high-speed blades, grinding, welding, or soldering can raise temperatures enough to cause thermal degradation of the foam. This danger is often overlooked during renovation work, placing contractors and occupants at risk.

Specialized detection equipment including multi-gas monitors capable of detecting hydrogen cyanide and isocyanates should be employed when working around installed foam in situations where heat might be generated. Standard carbon monoxide detectors are insufficient for capturing the full range of toxic emissions.

Best practices include maintaining a significant standoff distance between hot work and installed foam (typically at least 3 feet), using heat shields, and implementing continuous air monitoring. The Construction Safety Association recommends treating all foam as potentially toxic when exposed to heat above 200°F, regardless of manufacturer claims about flame retardance or low-toxicity formulations.

Comprehensive Ventilation Requirements

Proper ventilation stands as the primary engineering control for reducing both toxicity and flammability hazards in spray foam operations. OSHA and manufacturer guidelines typically specify a minimum of 10-30 air changes per hour during application, depending on the space volume and product being applied.

Effective ventilation systems must be designed specifically for the challenges of spray foam application. These systems should provide both supply and exhaust elements, creating directional airflow that moves contaminants away from workers and out of the building. The ventilation setup must prevent air recirculation within the structure, as this can spread contaminants to previously unaffected areas.

Post-application ventilation is equally critical. Most manufacturers recommend continuous ventilation for 24-48 hours after application, though the duration varies based on product formulation, applied thickness, ambient temperature, and humidity. Re-occupancy should be permitted only after testing confirms VOC levels have returned to safe baseline readings.

Methods for testing ventilation adequacy include smoke tubes to visualize airflow patterns, anemometers to measure air velocity, and differential pressure monitors to confirm negative pressurization of work areas. These assessments should be documented as part of the quality control process for each project.

Ventilation requirements for PU foam equipment operation must consider both applicator safety and downstream impacts. According to the American Industrial Hygiene Association, inadequate ventilation is consistently identified as a contributing factor in spray foam exposure incidents.

Essential Personal Protective Equipment (PPE)

The hazardous nature of spray foam chemicals necessitates comprehensive personal protection for all applicators. Respiratory protection requirements for spray foam application are more stringent than for many construction activities. At minimum, applicators should use a full-face or hood-style supplied air respirator (SAR) with clean air provided from a compressor or tanks.

Air-purifying respirators, even those with isocyanate-specific cartridges, are generally considered insufficient for spray foam application because isocyanates can penetrate filters and lack adequate warning properties (you can't smell them before they reach dangerous levels). The National Institute for Occupational Safety and Health (NIOSH) recommends supplied air systems with assigned protection factors of at least 1000 for isocyanate exposure.

Full-body protection must include chemical-resistant coveralls (typically Tyvek or similar material), with sealed connections at wrists, ankles, and the face piece of the respirator. These coveralls should be disposed of after each use rather than reused, as isocyanates can penetrate and remain active in fabric.

Chemical-resistant gloves specifically rated for isocyanates (typically nitrile or neoprene) and eye protection integrated with the respiratory system complete the ensemble. For PPE for toxic spray foam machine operation, nothing less than complete coverage with appropriate materials should be considered adequate.

Proper donning and doffing procedures are critical to prevent cross-contamination. Workers should put on coveralls first, then respirators, and finally gloves (which should overlap the coverall cuffs). Removal should proceed in reverse order, with care taken to avoid touching contaminated surfaces.

Respirator Fit Testing and Maintenance

Ensuring respiratory protection functions properly requires strict adherence to fit testing and maintenance protocols. All workers using tight-fitting respirators must undergo quantitative fit testing annually at minimum, with additional testing if significant weight changes, dental work, or facial surgeries occur. This testing verifies that the respirator creates a proper seal against the user's face.

Supplied air systems require regular inspection and maintenance, including compressor filter changes, air quality testing, and inspection of all hoses and connections. These systems should be maintained according to the manufacturer's schedule, with documentation of all maintenance activities preserved for regulatory compliance.

A comprehensive respiratory protection program must include written procedures, medical clearance for respirator users, proper storage facilities, and regular training. OSHA's Respiratory Protection Standard (29 CFR 1910.134) mandates specific elements that must be included in such programs.

Common failures in respiratory protection often stem from improper fit, failure to perform required maintenance, or shortcuts taken during busy periods. A study by NIOSH found that nearly 30% of respirators in field use had significant problems that compromised protection. Daily pre-use inspections can help identify many of these issues before they create exposure risks.

Safe Application Practices to Minimize Risks

Beyond proper equipment and PPE, specific application techniques significantly impact safety during spray foam installation. Proper mixing of components according to manufacturer specifications is crucial—improper ratios can lead to incomplete chemical reactions that increase both toxicity and fire hazards. Quality spray equipment with precise metering systems helps ensure proper mixing.

Environmental conditions play a major role in application safety. Temperature and humidity must fall within the manufacturer's specified ranges—typically 60-90°F and below 80% relative humidity. Operating outside these parameters can cause poor foam quality and increased emissions of volatiles.

Application thickness limitations are crucial for preventing excessive heat buildup. Most manufacturers specify a maximum thickness of 2 inches per pass to allow heat dissipation. Exceeding this limit can cause scorching, cracking, or even spontaneous combustion in extreme cases.

Re-entry timing must be strictly enforced. Unprotected workers should not enter application areas until chemical concentrations have fallen below established thresholds, typically 24 hours minimum. Building occupants may need to wait longer, with vulnerable populations like children and the elderly requiring the most conservative approach.

Site preparation to minimize contamination includes covering all surfaces not receiving foam application, establishing clear boundaries for the work zone, and communicating hazards to all personnel in the vicinity. Decontamination stations should be established at work zone exit points to prevent tracking chemicals to clean areas.

The foam material selection process should include safety considerations alongside performance criteria, with preference given to formulations with better safety profiles when application conditions permit.

Equipment Maintenance for Safety Assurance

Proper maintenance of spray foam equipment is not just about operational efficiency—it's a critical safety measure. Regular inspection protocols include checking hoses for wear, ensuring proper operation of heaters and pressure relief systems, and verifying that all safety interlocks function correctly. These inspections should follow a documented checklist and occur before each use.

Cleaning procedures prevent chemical buildup and cross-contamination between different foam formulations. Proper purging of the system with appropriate cleaning agents is essential, as residual chemicals can react unexpectedly when new materials are introduced. These cleaning operations themselves present chemical exposure risks and should be conducted with full PPE and ventilation.

Components with limited service life, such as spray tips, filters, and seals, require replacement according to manufacturer schedules rather than waiting for failure. These preventative replacements significantly reduce the risk of leaks or spray pattern issues that could increase exposure hazards.

Documentation of all maintenance activities creates an essential record for both safety compliance and troubleshooting. This documentation should include dates, procedures performed, parts replaced, and the technician responsible for the work.

Warning signs of equipment malfunction that demand immediate attention include unusual pressure fluctuations, temperature control problems, irregular spray patterns, or unusual odors. Any of these symptoms could indicate conditions that increase both toxicity and fire hazards.

Worker Training and Certification Requirements

The complexity and hazards of spray foam application require comprehensive training and formal certification. The Spray Polyurethane Foam Alliance (SPFA) offers industry-standard certifications for applicators at multiple levels, with safety training as a core component of all programs. Many manufacturers also provide product-specific training that addresses the unique characteristics of their systems.

New workers should complete both classroom and hands-on training before participating in actual applications. This training must cover chemical hazards, PPE use, ventilation requirements, fire safety, and emergency procedures. Written and practical examinations verify comprehension and skill development.

Refresher training should occur annually at minimum, with additional sessions whenever new equipment or materials are introduced. This ongoing education helps prevent complacency and ensures workers remain current on best practices and regulations.

Documentation of worker competency isn't just good practice—it's often a legal requirement. Many jurisdictions mandate specific training for workers handling isocyanates and other hazardous chemicals. This documentation should be maintained in personnel files and available for regulatory inspection.

Legal requirements for worker qualification vary by location but generally include hazard communication training, respirator training, and specific chemical safety education. Some regions require state-specific licenses or certifications for spray foam applicators, particularly for commercial projects.

Emergency Response Protocols

Despite preventative measures, emergencies can occur during spray foam operations. First aid procedures for chemical exposure should be clearly posted and regularly rehearsed. These procedures typically include immediate flushing of affected areas with water for at least 15 minutes for skin or eye contact, moving to fresh air for inhalation exposure, and seeking prompt medical attention.

Evacuation plans must account for the unique challenges of spray foam emergencies, including potentially impaired visibility from aerosols and the rapid spread of toxic fumes. Primary and alternate exit routes should be identified before work begins, with assembly points established upwind of the application area.

Containment procedures for chemical releases include using absorbent materials specifically rated for isocyanates and polyols, preventing chemicals from entering drains or waterways, and proper disposal of contaminated materials. These procedures must comply with local environmental regulations.

Incident reporting requirements include both internal documentation and notification of appropriate regulatory agencies when thresholds are exceeded. OSHA requires reporting of hospitalizations and chemical releases above reportable quantities, while EPA and local environmental agencies may have additional requirements.

Communication systems for emergencies should function even if normal power or cellular service is disrupted. Rally points, buddy systems, and emergency signals should be established before work begins and verified during safety briefings.

Regulatory Framework for Spray Foam Safety

Multiple regulatory bodies govern spray foam safety in the workplace. OSHA regulations most directly impact application operations, with standards addressing respiratory protection (29 CFR 1910.134), hazard communication (29 CFR 1910.1200), personal protective equipment (29 CFR 1910.132), and specific chemical exposures. These regulations establish legally enforceable minimum requirements for worker protection.

EPA guidelines focus on chemical exposure beyond the immediate workplace, including migration of chemicals to occupied spaces and environmental releases. The EPA's Chemical Action Plans for certain isocyanates highlight concerns about these chemicals and recommend specific control measures.

Building codes impact both application processes and the finished installation. Fire codes typically require specific ratings for foam insulation, especially in commercial structures. These codes may mandate thermal barriers over foam installations and limit where and how foam can be used in buildings.

Industry standards from organizations like the American Chemistry Council's Center for the Polyurethanes Industry (CPI) and the Spray Polyurethane Foam Alliance (SPFA) provide detailed best practices that often exceed regulatory minimums. These standards represent consensus among manufacturers, applicators, and safety professionals on optimal approaches.

International variations in safety regulations can impact global operations and imported equipment or materials. The European Union's REACH regulations and the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) may impose different or additional requirements compared to U.S. standards.

Monitoring and Testing Protocols

Ongoing monitoring provides objective verification that safety measures are working effectively. Air quality monitoring during and after application should include measurements of isocyanates, volatile organic compounds, and particulates. Modern direct-reading instruments can provide real-time data on chemical concentrations, allowing for immediate corrective action if levels approach dangerous thresholds.

Medical surveillance programs for workers regularly exposed to spray foam chemicals typically include baseline pulmonary function tests, periodic health questionnaires, and follow-up testing if symptoms develop. These programs help identify health effects early, before they become severe or irreversible.

Documentation of exposure levels should be maintained for each worker and project. This documentation serves both regulatory compliance and worker health tracking purposes. OSHA requires that exposure records be maintained for 30 years due to the long latency period of some chemical-related illnesses.

Technologies for real-time chemical detection continue to advance, with newer systems offering greater sensitivity, specificity, and ease of use. These technologies help ensure that workers aren't relying solely on administrative controls or PPE for protection.

Interpreting test results requires specialized knowledge of occupational hygiene principles. Results must be compared to appropriate standards, accounting for sampling duration, analytical methods, and applicable exposure limits. When results indicate problems, a systematic investigation should identify root causes rather than merely treating symptoms.

Mitigating Long-term Health Risks

Beyond immediate hazards, spray foam operations present potential long-term health concerns that require strategic mitigation. Medical monitoring programs represent a proactive approach to worker health, establishing baselines and tracking changes over time. These programs should include respiratory function testing and allergy assessments at regular intervals.

Early intervention strategies for workers showing signs of sensitization can prevent progression to more severe conditions. This may include job modification, enhanced protective measures, or in some cases, transfer to positions without chemical exposure. The key is identifying problems before permanent sensitization occurs.

Career longevity considerations are important in an industry where chemical exposure is inevitable. Many experienced applicators adopt rotation schedules between spraying and non-spraying tasks to reduce cumulative exposure over their careers. Companies should support these approaches rather than having dedicated spray personnel who bear the full exposure burden.

Research on long-term health outcomes for spray foam workers remains limited but growing. Some studies suggest elevated rates of occupational asthma and other respiratory conditions among long-term applicators, highlighting the importance of comprehensive protection throughout a career.

Emerging technologies to reduce exposure risk include robotic application systems, improved containment methods, and advanced real-time monitoring. The industry continues to develop less hazardous formulations, though true "non-toxic" spray foam remains elusive at commercial scale.

Future Directions: Safer Spray Foam Technologies

The spray foam industry continues to evolve toward safer formulations and application methods. Development of low-VOC and non-isocyanate formulations represents perhaps the most significant advancement on the horizon. Several manufacturers have introduced products with reduced isocyanate content or alternative chemistry, though these typically involve trade-offs in performance or cost.

Engineering controls to minimize exposure continue to improve, with newer spray enclosures, extraction systems, and containment technologies making it easier to isolate the application process from workers and occupants. These systems increasingly incorporate automated monitoring and alarm features that alert workers to developing hazards.

Automated application systems, including robotic sprayers and mechanical application arms, can remove workers from direct exposure zones while maintaining application quality. Though currently used primarily in industrial settings, these technologies are becoming more accessible for field applications.

Enhanced PPE technologies including improved vapor barriers, more comfortable supplied air systems, and better integration between components make protection more effective and more likely to be used consistently. New materials with superior chemical resistance and breathability improve worker comfort during long application sessions.

Industry initiatives for continuous safety improvement include sharing of incident data, collaborative research on exposure reduction, and standardization of safety protocols across manufacturers. These cooperative efforts recognize that safety advancement benefits all stakeholders in the spray foam industry.

Conclusion: Balancing Benefits and Risks

Understanding the toxicity and flammability profiles of PU spray foam machines and materials is essential for anyone working with this technology. The chemical complexity of these systems creates genuine hazards that require respect and proper management. From isocyanate toxicity to fire hazards during application, these risks are significant but can be effectively controlled through proper practices.

The importance of comprehensive training, appropriate equipment selection, and rigorous procedures cannot be overstated. Each element of the safety system—from ventilation to PPE to emergency response—plays a critical role in reducing risk to acceptable levels. Missing or compromising any component can undermine the entire protection strategy.

Safe handling of flammable spray foam materials requires understanding both the chemistry and the application process. By implementing appropriate engineering controls, work practices, and personal protection, contractors can successfully manage fire hazards in polyurethane foam application while still achieving high-quality installations.

By embracing both the letter and spirit of safety regulations, spray foam contractors demonstrate professionalism and commitment to their craft. This approach protects workers, clients, and the industry's reputation while delivering the remarkable performance benefits that make spray foam an increasingly popular insulation choice.

Frequently Asked Questions

How toxic are the chemicals in PU spray foam machines?

The isocyanates in spray foam are classified as highly toxic chemicals that can cause respiratory sensitization, asthma, and other health problems. Exposure without proper protection can lead to both acute and chronic health issues, with some workers developing permanent sensitization that prevents further work with these materials.

Can spray foam catch fire during application?

Yes, spray foam components can be flammable during application. The chemical reaction generates heat, and some components have relatively low flash points. Ignition sources must be eliminated from the work area, and proper application techniques must be followed to prevent excessive heat buildup that could lead to combustion.

How long should an area be ventilated after spray foam application?

Most manufacturers recommend continuous ventilation for 24-48 hours after application, though this varies based on the specific product, application thickness, and environmental conditions. Re-entry should be permitted only after testing confirms chemical levels have returned to safe baselines.

What type of respirator is required for spray foam application?

At minimum, a full-face or hood-style supplied air respirator (SAR) with clean air provided from a compressor or tanks is required. Air-purifying respirators, even with isocyanate-specific cartridges, are generally considered insufficient for spray foam application due to isocyanates' ability to penetrate filters.

Are "green" or "eco-friendly" spray foams less toxic?

While some "green" formulations may have reduced VOC content or eliminate certain chemicals of concern, all professional spray foam systems still contain chemicals that require proper safety precautions. No spray foam system is entirely free from potential health hazards during application.

Can cured spray foam still present health or fire hazards?

Yes, cured foam can still present hazards under certain conditions. If exposed to high heat (from cutting, grinding, welding, etc.), cured foam can release toxic decomposition products and potentially ignite. Under normal conditions, properly cured and installed foam presents minimal risks to building occupants.

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